4.6 Article

Crystal structure and multiferroic properties of Gd-substituted BiFeO3

Journal

APPLIED PHYSICS LETTERS
Volume 93, Issue 26, Pages -

Publisher

AIP Publishing
DOI: 10.1063/1.3058708

Keywords

antiferromagnetic materials; bismuth compounds; crystal structure; ferroelectric materials; gadolinium compounds; multiferroics; solid-state phase transformations; spontaneous magnetisation; X-ray diffraction

Funding

  1. Foundation for Science and Technology (FCT) of Portugal [SFRH/BPD/26163/2005]
  2. Deutsche Forschungsgemeinschaft (DFG) [SFB 491]
  3. Multiceral [NMP3-CT-2006-032616]
  4. FAME Network of Excellence [NMP3-CT-2004-500159]

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Room-temperature crystal structure, local ferroelectric, and magnetic properties of the Bi1-xGdxFeO3 (x=0.1,0.2,0.3) polycrystalline samples have been investigated by x-ray diffraction, piezoresponse force microscopy, and magnetometry techniques. Performed measurements have revealed a sequence of the composition-driven structural phase transitions R3c -> Pn2(1)a (occurs at x similar to 0.1) and Pn2(1)a -> Pnma (takes place within the concentrational range of 0.2 < x < 0.3). The latter structural transformation is attributed to the substitution-induced suppression of the polar displacements. Gd substitution has been shown to effectively induce the appearance of the spontaneous magnetization, thus indicating a promising way for improving multiferroic properties of antiferromagnetic BiFeO3.

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