Journal
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Volume -, Issue 23, Pages 4550-4553Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.200400546
Keywords
surface analysis; cyclic voltammetry; immobilization; rhenium; oxidation
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A high-valent trans-dioxorhenium(V) complex containing pyridine ligands was successfully immobilized on an ITO (indium-doped tin-oxide) electrode. The complex formed a monolayer structure on the electrode surface and promoted electrochemical catalytic oxidation of 1-phenylethanol to acetophenone in CH2Cl2. Oxidation hardly occurred in CH2Cl2 solution containing the free rhenium(v) complex. Immobilization of other high-valent metal complexes will present opportunities for design of functional electrodes with high activities. (C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004.
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