Stabilized leachates:: sequential coagulation-flocculation plus chemical oxidation process

The combined sedimentation-chemical oxidation treatment of medium-stabilized landfill leachates has been investigated. The sequence of stages implemented was: (a) coagulation-flocculation by pH decrease (pH 2) to acidic conditions (COD removal approximate to 25% related to COD0 approximate to 7500 ppm); (b) coagulation-flocculation by Fe(Ill) addition (0.01 M) at pH 3.5 (COD removal approximate to 40% related to COD of supernatant after step (a); (c) Fenton (Fe(III) = 0.0 1 M; H2O2 = 1.0 M) oxidation (COD removal approximate to 80% related to COD of supernatant after step (a); and (d) coagulation-flocculation of Fenton's effluent at pH 3.5 (COD removal approximate to 90% related to COD of supernatant after step (a). The use of Kynch theory allows for the design of clarifiers based on the amount of solids fed. For a general example of 1000 m(3) day(-1) of a feeding stream, clarifier area values of 286, 111 and 231 m(2) were calculated for compacting indices of 3.7, 2.67 and 2.83 corresponding to the first, second and third consecutive sedimentation processes, respectively, (steps (a), (b) and (d)). (C) 2004 Elsevier B.V. All rights reserved.