Journal
TETRAHEDRON
Volume 60, Issue 51, Pages 11743-11749Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2004.10.003
Keywords
electrolysis; stereoselectivity; electrocatalytic transformation; mediators; malononitrile; arylidenemalononitriles; bicyclic pyrrolines
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Electrolysis of arylidenemalononitriles and malononitrile in alcohols in an undivided cell in the presence of sodium bromide as mediator results in the stereoselective formation of (1R,2S,6R)*-6-aryl-2-amino-4,4-dialkoxy-1,5-dicyano-3-azabicyclo[3. 1.0]hex-2-enes in 60-80% yields. (C) 2004 Elsevier Ltd. All rights reserved.
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