Journal
JOURNAL OF CHEMICAL PHYSICS
Volume 121, Issue 23, Pages 12100-12103Publisher
AMER INST PHYSICS
DOI: 10.1063/1.1824013
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A new dynamical definition of the effective colloidal charge, especially suitable for the Monte Carlo and Molecular-dynamics simulations, is proposed. It is shown that for aqueous colloidal suspensions containing monovalent counterions the dynamical effective charge agrees perfectly with the statistical effective charge calculated using the Alexander prescription. In the case of multivalent ions, the effective charge behaves in a qualitatively different way from the predictions of the Poisson-Boltzmann theory. (C) 2004 American Institute of Physics.
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