Journal
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
Volume 224, Issue 1-2, Pages 189-195Publisher
ELSEVIER
DOI: 10.1016/j.molcata.2004.08.048
Keywords
vanadium catalysts; hydroxylation; oxidation; hydrogen peroxide; benzene; mesitylene; aromatics; Amavadine
Categories
Ask authors/readers for more resources
Benzene and mesitylene (1,3,5-trimethylbenzene) are oxidized to phenol and to the corresponding aldehyde (3,5-dimethylbenzaldehyde), respectively. in CH3CN at room temperature, by aqueous hydrogen peroxide, in acidic medium, in reactions catalyzed by vanadium(IV or V) compounds with N,O-ligands (such as Amavadine models and related ones), namely of the types triethanolamine and (hydroxy-imino)dicarboxylic acid (basic forms) or comparable ligands. The effects of the ligands, of the relative amounts of reagents and of the temperature are also reported. (C) 2004 Elsevier B.V. All rights reserved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available