Journal
ORGANOMETALLICS
Volume 23, Issue 26, Pages 6231-6238Publisher
AMER CHEMICAL SOC
DOI: 10.1021/om049292t
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Treatment of hydroquinone with [Cp*M(solvent)3] [OTf](2) (M = Rh, Ir) in acetone afforded the T-bonded complexes {[Cp*M(eta(5)-semiquinone)] [OTf]}(n) (M = Rh (1a), M = Ir (1b)) in 95% yield. The H-1 NMR spectra of 1a,b recorded in CD3OD indicate strong hydrogen bonding in solution. The crystal structures of 1a and 1b were determined and exhibit strong intermolecular hydrogen bonding, forming organometallic polymers in which the integrity of the system is maintained by hydrogen bonding between metal-semiquinone subunits. Deprotonation of 1a produced the related eta(4)-quinone complex [Cp*Rh(eta(4)-quinone)] (2a), which was fully characterized and its X-ray molecular structure determined. Furthermore, the electrochemical behavior of these eta(4) -quinone pi-complexes [Cp*M(eta(4)-quinone)] (M = Rh (2a), M = Ir (2b)) was investigated and compared to that of the well-known couple quinone/ hydroquinone. The latter are important species in chemistry and biology; their biological action is often linked to their electron-transfer rates and redox behavior.
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