Journal
MACROMOLECULAR RAPID COMMUNICATIONS
Volume 25, Issue 24, Pages 2008-2013Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/marc.200400403
Keywords
clay; nanocomposites; poly(propylene) (PP); Ziegler-Natta catalysts
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Poly(propylene)/monoalkylimidazolium-modified montmorillontie (PP/IMMT) nanocomposites were prepared by in situ intercaltive polymerization of propylene with TiCl4/MgCl2/MMT catalyst. The PP synthesized possessed high isotacticity and molecular weight. Both wide-angle X-ray diffraction (XRD) and transmission electron microscopy (TEM) examinations evidenced the nanocomposite formation with exfoliated MMT homogeneously distributed in the PP matrix. A thermal stability study revealed that the nanocomposites possess good thermal stability.
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