Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 126, Issue 51, Pages 17050-17058Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja046780j
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A molecular capsule based on ionic interactions between two oppositely charged calix[4]arenes, 1 and 2, was assembled both in solution and on a surface. In solution, the formation of the equimolar assembly 1(.)2 was studied by H-1 NMR, ESI-MS, and isothermal titration calorimetry, giving an association constant (K-a) of 7.5 x 10(5) M-1. A beta-cyclodextrin self-assembled monolayer (beta-CD SAM) on gold was used as a molecular printboard to anchor the tetraguanidinium calix[4]arene (2). The binding of tetrasulfonate calix[4]arene 1 was monitored by surface plasmon resonance spectroscopy. Rinsing of the surface with a high ionic strength aqueous solution allows the removal of the tetrasulfonate calix[4]arene (1), while by rinsing with 2-propanol it is possible to achieve the complete desorption of the tetraguanidinium calix[4]-arene (2) from the beta-CD SAM. The Ka for the capsule formation on a surface is 3.5 x 106 M-1, thus comparing well with the Ka determined in solution.
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