Journal
TETRAHEDRON LETTERS
Volume 46, Issue 1, Pages 157-159Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2004.10.168
Keywords
allylation; catalys; enantioselectivity; phosphine oxide
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The effectiveness of chiral phosphine oxide BINAPO as a catalyst for the enantio elective addition of allyltrichlorosilanes to aldehydes was demonstrated, wherein the combination of diisopropylethylamine and tetrabutylammonium iodide as additives is crucial for accelerating the catalytic cycle. (C) 2004 Elsevier Ltd. All rights reserved.
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