Journal
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
Volume 225, Issue 1, Pages 111-116Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.molcata.2004.08.035
Keywords
alcohol oxidation; aqueous catalysis; water-soluble palladium complex
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An aqueous palladium catalyst that is stabilized by a water-soluble biquinoline-based ligand was employed for the aerobic oxidation of secondary and primary alcohols. Secondary alcohols afforded the corresponding ketones in high yield with selectivities greater than 90%. Aliphatic primary alcohols were fully oxidized to carboxylic acid products under the same reaction conditions, with various amounts of ester byproduct. Benzyl alcohol can be converted to a mixture of benzaldehyde and benzoic acid, where the relative amounts are dependent on the reaction conditions, while substituted benzylic alcohols gave primarily benzaldehyde derivatives. In contrast to related systems, the catalyst used in this study is tolerant of additional coordinating groups on the benzyl alcohol substrate. In all examples of alcohol oxidation, water is used as the only reaction solvent and air is used as the oxidant, thus these conversions could serve as environmentally benign green alternatives to traditional oxidation methods. (C) 2004 Elsevier B.V. All rights reserved.
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