Journal
ORGANIC LETTERS
Volume 7, Issue 1, Pages 147-150Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol047739o
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Using reaction rate data collected in aprotic solvents, we have determined that the Baylis-Hillman rate-determining step is second order in aldehyde and first order in DABCO and acrylate. On the basis of these data, we have proposed a new mechanism involving a hemiacetal intermediate. The proposed mechanism was then supported using two different kinetic isotope experiments.
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