Journal
JOURNAL OF POWER SOURCES
Volume 140, Issue 1, Pages 81-87Publisher
ELSEVIER
DOI: 10.1016/j.jpowsour.2004.08.009
Keywords
Co3O4 coating; porous nickel cathode; molten carbonate; fuel cell; XRD; Raman spectroscopy; XPS; porosity
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Porous nickel cathode was protected by potentiostatically deposited cobalt at different experimental conditions: oxidation potential and electrolysis duration. The deposition growth increased with the oxidation potential yielding a more developed granular structure with smaller grains. Thin layers of Co3O4 were identified by X-ray diffraction (XRD) and Raman spectroscopy. CoOOH was detected by X-ray photoelectron spectroscopy (XPS) before annealing treatment and Co3O4 after heating the sample at 500 C during 4 h in air. After this treatment, some morphological changes were observed on the coated samples due to grain compaction and oxidation of the nickel substrate. The porosity of the coated samples was relatively close to that of the sole porous nickel. These coatings exhibited an appropriate dual-pore structure with macro and micro pores, a basic MCFC requirement. (C) 2004 Elsevier B.V. All rights reserved.
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