Journal
TETRAHEDRON LETTERS
Volume 46, Issue 3, Pages 401-405Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2004.11.109
Keywords
amino sugar; calpain inhibitor; enkephalin; overman rearrangement; peptidomimetic
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A stereocontrolled synthesis of an unsaturated sugar bearing two amino groups (one of them masked as an azide), using an Overman rearrangement as key step, is described. This scaffold is used to prepare two peptides having aromatic fragments. which have shown activity as calpain inhibitors. (C) 2004 Elsevier Ltd. All rights reserved.
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