Journal
TETRAHEDRON-ASYMMETRY
Volume 16, Issue 2, Pages 433-439Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetasy.2004.11.029
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Application of two classes of thioimidoyl derivatives, S-benzoxazolyl (SBox) and S-thiazolyl (STaz) glycosides to selective activation over thioglycosides is described. These results allowed us to synthesize a tetrasaccharide derivative using a leaving group differentiated one-pot strategy in 73% yield over three sequential glycosylation steps. (C) 2004 Elsevier Ltd. All rights reserved.
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