Journal
APPLIED PHYSICS LETTERS
Volume 86, Issue 4, Pages -Publisher
AMER INST PHYSICS
DOI: 10.1063/1.1854218
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We theoretically identify the chemical thermodynamic boundary conditions that will produce n-type CuInSe2 via halogen doping. Remarkably, we find that due to the low formation energies of the intrinsic defects, V-Cu and In-Cu in CuInSe2, the growth conditions that maximize the halogen donor incorporation do not yield n-type conductivity, whereas the conditions that maximize the concentration of the intrinsic donor In-Cu do yield n-type conductivity. Under the latter conditions, however, the contribution of the halogen donors to the net donor concentration stays significantly below that of In-Cu. (C) 2005 American Institute of Physics.
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