Journal
INORGANIC CHEMISTRY
Volume 44, Issue 2, Pages 181-183Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic048612y
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Two metal-organic frameworks (MOFs), MOF-501 and MOF-502, respectively, formulated as Co-2(BPTC)(H2O)(5)(.)G(x), and Co-2(BPTC)-(H2O)(DMF)(2)(.)G(x) (BPTC = 3,3',5,5'-biphenyltetracarboxylate; G = guest molecules), have been synthesized and structurally characterized, and their topologies were found to be based on the NbO (MOF-501) and PtS (MOF-502) nets. Heating MOF-501 in solution results in the more thermodynamically favored MOF-502.
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