Journal
ADVANCED MATERIALS
Volume 17, Issue 2, Pages 205-+Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.200400607
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Microspheres of wax containing embedded Grubbs' catalyst are generated by congealing a molten aqueous suspension. Even with a ten-fold reduction in catalyst concentration from previous systems, these microspheres produce unprecedented levels of toughness recovery in a polymeric self-healing material (see Figure). Unlike the previously reported systems, samples healed with the wax microspheres show nonlinear fracture behavior. A protocol that addresses this nonlinearity is employed to measure healing efficiency.
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