Synthesis and characterization of Sr1-xMgxTiO3 obtained by the polymeric precursor method

Strontium titanate (SrTiO3; STO), a semiconductor displaying the perovskite structure, has been extensively studied, both as thin films and as powders, due to its high dielectric constant, good capacitance, and other properties. In the present work, the synthesis of Mg-substituted SrTiO3 powders was studied using the polymeric precursor method. This method, also known as the Pechini method, has many advantages such as chemical homogeneity of multicomponents at the molecular scale and a direct and precise control of stoichiometry in complex systems at relatively low temperatures. The powders were characterized by thermogravimetry (TG)/differential thermal analysis (DTA). After the heat treatment between 600 and 1000 degreesC, the powders were characterized by X-ray diffraction (XRD) and infrared spectroscopy (IR). Thermal analysis results indicate successive exothermic and endothermic steps. After crystallization, a single-phase material was obtained for samples containing less than 20 % of Mg. The crystallite size was nanometric and a high crystallinity was obtained. Infrared spectroscopy indicated vibration bands characteristic of carbonates and metallic oxides. (C) 2004 Elsevier B.V. All rigths reserved.