Journal
SYNTHESIS-STUTTGART
Volume -, Issue 2, Pages 260-266Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-2004-837297
Keywords
carbohydrates; glycosides; glycosylations; rearrangements; synthesis
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Alkyl 2,3-unsaturated glycopyranosides have been prepared by the Ferrier rearrangement of acetyl protected glycals catalyzed by HClO4-SiO2. Operational simplicity, use of economically convenient catalyst, mild reaction conditions, high yields, short reaction times are the key features of this protocol.
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