Journal
CANADIAN JOURNAL OF CHEMISTRY
Volume 83, Issue 2, Pages 115-121Publisher
CANADIAN SCIENCE PUBLISHING
DOI: 10.1139/V05-008
Keywords
sulfoxides; sulfones; oxidation; chlorochromate; Lewis acid
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3-Carboxypyridinium chlorochromate (CPCC) in the presence of aluminium chloride is a very efficient reagent for the selective oxidation of sulfides to sulfoxide and sulfones in solution and under microwave irradiation. It is noteworthy that different functional groups including carbon-carbon double bonds, ketones, oximes, aldehydes, ethers, and acetals were tolerated under these reaction conditions.
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