Journal
APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING
Volume 117, Issue 1, Pages 25-29Publisher
SPRINGER HEIDELBERG
DOI: 10.1007/s00339-014-8311-9
Keywords
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Funding
- European Community [308975]
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A laser-induced periodic surface structure (LIPSS) has been fabricated on polycrystalline diamond by an ultrashort Ti:Sapphire pulsed laser source (lambda = 800 nm, P = 3 mJ, 100 fs) in a high vacuum chamber (< 10(-7) mbar) in order to increase diamond absorption in the visible and infrared wavelength ranges. A horizontally polarized laser beam had been focussed perpendicularly to the diamond surface and diamond target had been moved by an automated X-Y translational stage along the two directions orthogonal to the optical axis. Scanning electron microscopy of samples reveals an LIPSS with a ripple period of about 170 nm, shorter than the laser wavelength. Raman spectra of processed sample do not point out any evident sp (2) content, and diamond peak presents a right shift, indicating a compressive stress. The investigation of optical properties of fs-laser surface textured diamond is reported. Spectral photometry in the range 200/2,000 nm wavelength shows a significant increase of visible and infrared absorption (more than 80 %) compared to untreated specimens (less than 40 %). The analysis of optical characterization data highlights a close relationship between fabricated LIPSS and absorption properties, confirming the optical effectiveness of such a treatment as a light-trapping structure for diamond: these properties, reported for the first time, open the path for new applications of CVD diamond.
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