Soot concentration and temperature measurements in co-annular, nonpremixed CH4/air laminar flames at pressures up to 4 MPa

Laminar nonpremixed methane-air flames were studied over the pressure range of 0.5 to 4 MPa using a new high-pressure combustion chamber. Flame characterization showed very good flame stability over the range of pressures, with a flame tip rms flicker of less than 1% in flame height. At all pressures, soot was completely oxidized within the visible flame. Spectral soot emission (SSE) and line-of-sight attenuation (LOSA) measurements provided radially resolved measurements of soot volume fraction and soot temperature at pressures from 0.5 to 4.0 MPa. Such measurements provide an improved understanding of the influence of pressure on soot formation and have not been reported previously in laminar nonpremixed flames for pressures above 0.4 MPa. SSE and LOSA soot concentration values typically agree to within 30% and both methods exhibit similar trends in the spatial distribution of soot concentration. Maximum soot concentration depended on pressure according to a power law, where the exponent on pressure is about 2 for the range of pressures between 0.5 and 2.0 MPa, and about 1.2 for 2.0 to 4.0 MPa. Peak carbon conversion to soot also followed a power-law dependence on pressure, where the pressure exponent is unity for pressures between 0.5 and 2.0 MPa and 0.1 for 2.0 to 4.0 MPa. The pressure dependence of sooting propensity diminished at pressures above 2.0 MPa. Soot concentrations measured in this work, when transformed to line-integrated values, are consistent with the measurements of Flower and Bowman for pressures up to 1.0 MPa [Proc. Combust Inst. 21 (1986) 1115-1124] and Lee and Na for pressures up to 0.4 MPa [JSME Int. J. Ser. B 43 (2000) 550-555]. Soot temperature measurements indicate that the overall temperatures decrease with increasing pressure; however, the differences diminish with increasing height in the flame. Low down in the flame, temperatures are about 150 K lower at pressures of 4.0 MPa than those at 0.5 MPa. In the upper half of the flame the differences reduce to 50 K. Crown Copyright (c) 2004 Published by Elsevier Inc. on behalf of The Combustion Institute. All rights reserved.