Journal
APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING
Volume 114, Issue 2, Pages 291-295Publisher
SPRINGER
DOI: 10.1007/s00339-013-8048-x
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Funding
- DFG [SPP1355, SFB951]
- Helmholtz-Energie-Allianz Hybrid-Photovoltaik
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We show how the work function of transparent conductive oxide surfaces can be increased by more than 1 eV by solution-depositing strong electron acceptor monolayers comprising tetrafluoro-tetracyanoquinodimethane (F4TCNQ) or hexaazatriphenylene-hexacarbonitrile (HATCN). The effects of ambient atmosphere on the work function are investigated by comparing Kelvin probe measurements in air and ultraviolet photoelectron spectroscopy in ultrahigh vacuum. In this way, important technological issues related to the influence of ambient moisture on electrode properties are elucidated.
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