Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 70, Issue 3, Pages 797-801Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo048239b
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The synthesis of a bis(pyridyl)-substituted perylene diimide ligand and its incorporation into a supramolecular rhomboid and rectangle via platinum-mediated self-assembly is reported. Both ensembles are characterized by multinuclear NMR and electrospray ionization mass spectrometry. In addition, the UV/vis spectra of the ensembles exhibit displaced and enhanced absorptions relative to the starting ligand. Size estimations using MM2 simulations show the assemblies are almost 46 Angstrom in length.
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