Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2005, Issue 4, Pages 706-711Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.200400616
Keywords
carbohydrates; glycosylation; remote participation; stereoselective synthesis
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The stereoselectivity of beta-mannosylation can be improved with the use of a participating moiety at C-4 (O-anisoyl, O-thiocarbamoyl). This improvement was achieved in glycosidations of S-ethyl and, especially, S-benzoxazolyl (SBox) mannosides. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)
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