Investigation of the filamentary and diffuse mode of barrier discharges in N2/O2 mixtures at atmospheric pressure by cross-correlation spectroscopy

The techniques of spatially resolved cross-correlation spectroscopy (CCS) and current pulse oscillography were used to carry out systematic investigations of the barrier discharge (BD) in the binary gas mixtures N-2/O-2 at atmospheric pressure. At very low oxygen concentrations (< 500 ppm), the 131) was observed in a so-called diffuse mode (also referred to as atmospheric pressure glow discharge, glow silent discharge or homogeneous 131)). In the case of the BD filamentary mode, the spatio-temporal distributions of the BD radiation intensities were recorded for the spectral bands of the 0-0 transitions of the second positive (lambda = 337 nm) and first negative system of molecular nitrogen (lambda = 391 nm). In the case of the diffuse mode, the spectral bands lambda = 337 nm, lambda = 260 nm (0-3 transition of the gamma-system of NO) and lambda = 557 nm (radiation of ON2 excimer) were used for this purpose. The velocities of the cathode-directed ionizing waves as well as the effective lifetimes of the excited states N-2 (C-3 Pi(u))(nu'=0) and N-2(+)(B-2 Sigma(+)(u))(v'=0) were evaluated from the CCS data. Special attention was devoted to the investigation of the transition between the filamentary and diffuse modes of the BD, this transition being caused by the variation of oxygen content within the range 500-1000 ppm.