4.6 Article

Metal-organic framework MIL-125(Ti) for efficient adsorptive removal of Rhodamine B from aqueous solution

Journal

APPLIED ORGANOMETALLIC CHEMISTRY
Volume 29, Issue 1, Pages 12-19

Publisher

WILEY-BLACKWELL
DOI: 10.1002/aoc.3237

Keywords

MIL-125(Ti); adsorption; Rhodamine B; mechanism; adsorption isotherm

Funding

  1. science and technology key project of Fujian [2013H0053]
  2. Nature Science Foundation of Fujian [2012J06005]
  3. Natural Science Foundation of Zhangzhou [ZZ2012J01]
  4. Key Laboratory of Urban Environment and Health, Institute of Urban Environment, Chinese Academy of Sciences [KLUEH201305]

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A metal-organic framework material, MIL-125(Ti), was solvothermally prepared and characterized using X-ray diffraction, scanning electron microscopy, Fourier transform infrared spectroscopy and surface area measurements. MIL-125(Ti) was then used as an adsorbent for Rhodamine B (RhB) removal in aqueous solution. The adsorption kinetics, adsorption mechanism, adsorption isotherm, activation energy and various thermodynamic parameters were studied in detail. The maximum adsorption capacity of MIL-125(Ti) for RhB was 59.92mgg(-1). MIL-125(Ti) appears to be a promising material for RhB adsorption from aqueous solutions. Copyright (c) 2014 John Wiley & Sons, Ltd.

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