Journal
APPLIED ORGANOMETALLIC CHEMISTRY
Volume 29, Issue 2, Pages 96-100Publisher
WILEY
DOI: 10.1002/aoc.3251
Keywords
desulfurization; metal-organic framework; acidic catalyst; oxidation catalysis
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Funding
- Program for Professor of Special Appointment (Eastern Scholar) at Shanghai Institutions of Higher Learning
- Scientific Research Foundation for the Returned Overseas Chinese Scholars, State Education Ministry
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In this study, a Zrmetal-organic framework (UIO-66) was synthesized with zirconium tetrachloride and terephthalic acid using the solvent method. Then various masses of 1-methylimidazolium-3-propylsulfonate hydrosulfate (PSMIMHSO4) were supported on the UIO-66 as catalysts, which were used for catalytic oxidative desulfurization. Sulfur removal using 400mg of 40% PSMIMHSO4 supported on the UIO-66 of greater than 94% was obtained at 313 K for 20 min with an O/S molar ratio of 7:1. The results obtained in this work could provide useful information for the design of water-stable metal-organic frameworks with permanent porosity in applications of catalytic oxidative desulfurization. Copyright (C) 2014 John Wiley & Sons, Ltd.
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