4.6 Article

Recyclable 1,2-bis[3,5-bis(trifluoromethyl)phenyl]diselane-catalyzed oxidation of cyclohexene with H2O2: a practical access to trans-1,2-cyclohexanediol

Journal

APPLIED ORGANOMETALLIC CHEMISTRY
Volume 28, Issue 8, Pages 652-656

Publisher

WILEY
DOI: 10.1002/aoc.3175

Keywords

selenium; catalysis; trans-1,2-cyclohexanediol; oxidation

Funding

  1. NNSFC [21202141, 21202151, 20902070]
  2. Opening Foundation of the Key Laboratory of Environmental Materials and Engineering of Jiangsu Province [K11024]
  3. Priority Academic Program Development of Jiangsu Higher Education Institutions
  4. 580 Oversea Talents Program of Wenzhou City
  5. Jiangsu Yangnong Chemical Group Co. Ltd

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1,2-Bis[3,5-bis(trifluoromethyl)phenyl]diselane-catalyzed oxidation of cyclohexene by hydrogen peroxide affords a quick, clean and practical access to the important compound trans-1,2-cyclohexanediol under mild conditions. The highly atom-economic properties, clean procedures, high reaction concentration, short reaction time, mild conditions and eco-friendly, recyclable and low loading catalysts facilitate this methodology for possible future practical industrial production. Copyright (C) 2014 John Wiley & Sons, Ltd.

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