Journal
APPLIED ORGANOMETALLIC CHEMISTRY
Volume 27, Issue 7, Pages 412-418Publisher
WILEY-BLACKWELL
DOI: 10.1002/aoc.2997
Keywords
palladated catalyst; Suzuki reaction; Stille reaction; Hiyama reaction; biaryls
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Funding
- Isfahan University of Technology (IUT), IR Iran
- Isfahan Science and Technology Town (ISTT), IR Iran
- Center of Excellence in Sensor and Green Chemistry Research (IUT)
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The catalytic activity of dimeric [Pd{C6H2(CH2CH2NH2)-(OMe)2,2,3}(-Br)]2 and monomeric [Pd{C6H2(CH2CH2NH2)-(OMe)2,2,3}Br(PPh3)] complexes as efficient, stable and air- and moisture-tolerant catalysts was investigated in the Suzuki, Stille and Hiyama cross-coupling and homo-coupling reactions of various aryl halides. Substituted biaryls were produced in excellent yields in short reaction times using catalytic amounts of these complexes. The monomeric complex was demonstrated to be more active than the corresponding dimeric catalyst for the cross-coupling reaction of unreactive aryl bromides and chlorides. The combination of homogeneous metal catalysts and microwave irradiation gave higher yields of products in shorter reaction times. Copyright (c) 2013 John Wiley & Sons, Ltd.
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