Journal
APPLIED ORGANOMETALLIC CHEMISTRY
Volume 26, Issue 1, Pages 21-26Publisher
WILEY
DOI: 10.1002/aoc.1859
Keywords
oxidation; sulfides; Fe2(SO4)3; t-BuOOH; enantioselectivity
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Funding
- Department of Chemistry, Indian Institute of Technology Madras
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A variety of sulfides were converted to the corresponding sulfoxide derivatives with 70% t-BuOOH (water) as the oxidant in the presence of catalytic quantity of Fe2(SO4)3. The method described has a wide range of applications, involves simple work-up, exhibits chemoselectivity/enantioselectivity and proceeds under mild reaction conditions. The resulting products are obtained in good yield within a reasonable time. Copyright (C) 2012 John Wiley & Sons, Ltd.
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