Journal
APPLIED ORGANOMETALLIC CHEMISTRY
Volume 26, Issue 8, Pages 430-437Publisher
WILEY
DOI: 10.1002/aoc.2877
Keywords
1-(a-aminobenzyl)-2-naphthols; phosphine-free Suzuki reaction; homogeneous palladium catalysis; one-pot Wittig-Suzuki reaction
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Funding
- Council of Scientific and Industrial Research (CSIR) New Delhi
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Air stable and easily accessible, 1-(alpha-aminobenzyl)-2-naphthols are used as efficient phosphine-free ligands in palladium-catalyzed Suzuki reaction for a variety of substrates under conventional heating as well as ultrasonic conditions. Multi-brominated aromatic substrates were successfully converted to corresponding arylated moieties with good conversion and selectivity. A novel one-pot two-step cascade reaction strategy involving Wittig and Suzuki reactions is developed for efficient synthesis of 4-styryl biphenyls (C-6-C-2-C-6-C-6 unit). Copyright (c) 2012 John Wiley & Sons, Ltd.
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