Journal
APPLIED ORGANOMETALLIC CHEMISTRY
Volume 24, Issue 3, Pages 179-183Publisher
WILEY
DOI: 10.1002/aoc.1566
Keywords
organosilicon; sol-gel; hybrid material; Heck reaction
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A new catalytic system based on Pd supported on polyether-functionalized mesoporous silica was prepared. This material was obtained by co-hydrolysis and polycondensation of tetraethylorthosilicate and a bis-silylated triblock copolymer P123 (M-w = 5800) followed by the decomposition of Pd(OAc)(2) salt. We have shown that this material can be applied as powerful heterogeneous catalyst for the Heck coupling reaction. Copyright (C) 2009 John Wiley & Sons, Ltd.
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