Journal
LANGMUIR
Volume 21, Issue 5, Pages 1699-1702Publisher
AMER CHEMICAL SOC
DOI: 10.1021/la047217h
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A catalyst in the form of a capsule catalyst was prepared by coating HZSM(5) membrane on a preshaped CO/SiO2 catalyst pellet. The capsule catalyst with HZSM(5) membrane exhibited excellent selectivity for light hydrocarbon synthesis, especially for isoparaffin synthesis from syngas (CO + H-2). Long-chain hydrocarbon formation was totally suppressed by the zeolite membrane. The modification of membrane and core catalyst significantly improved the catalytic properties of these new kinds of capsule catalysts.
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