4.7 Article

Does electrical double layer formation lead to salt exclusion or to uptake?

Journal

PHYSICAL REVIEW E
Volume 71, Issue 3, Pages -

Publisher

AMER PHYSICAL SOC
DOI: 10.1103/PhysRevE.71.032501

Keywords

-

Ask authors/readers for more resources

When electric double layers are formed, cases have been reported where this formation involves expulsion of electrolyte into the solution and cases in which electrolyte is absorbed from the solution. Both situations are experimentally and theoretically documented, but they cannot be simultaneously correct. In this paper it is shown that this seeming conflict finds its cause in the way the double layer is formed: expulsion for double layers forming spontaneously by ion adsorption from the solution, but uptake when the double layer is formed by an external field. A thermodynamic analysis is presented.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.7
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

No Data Available
No Data Available