Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 70, Issue 5, Pages 1791-1795Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo0484023
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[GRAPHICS] A novel synthetic approach to the synthesis of enantiomerically pure 2,5-disubstituted pyrrolines is described. The methodology involves a Ag-catalyzed 5-endo-dig cyclization of enantiopure aryl-substituted acetylene-containing amino acids. It has also been shown that the obtained pyrrolines can be efficiently transformed into the corresponding saturated 5-aryl-substituted proline derivatives.
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