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Diastereoselective formation of α-aminoamides from carbamoylsilanes and aldehyde imines

TETRAHEDRON-ASYMMETRY (2005)

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Journal

TETRAHEDRON-ASYMMETRY
Volume 16, Issue 5, Pages 941-947

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetasy.2005.01.025

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Categories

Chemistry, Inorganic & Nuclear Chemistry, Organic Chemistry, Physical

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Diastereoselectivities were determined for the reaction of a series of aldehyde imines with carbamoylsilanes, each containing chiral auxiliaries at nitrogen. A maximum de of 88% was achieved via a matched double differentiation. (C) 2005 Elsevier Ltd. All rights reserved.

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