Journal
INORGANIC CHEMISTRY
Volume 44, Issue 5, Pages 1263-1274Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic048397l
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We report about the first X-ray structure analyses of the CS2 and CO2 adducts with carbodiphosphorane C(PPh3)(2) and the synthesis and X-ray structure analysis of group 6 carbonyl complexes with compound S2CC(PPh3)(2) as a ligand [(CO)(4)MS2CC(PPh3)(2)] (M = Cr, Mo, W). The nature of the carbon-carbon bonding in X2CC(PPh3)(2) and in the model compounds X2CC(PH3)(2) and the metal-ligand bonding in [(CO)(4)MoS2CC(PH3)(2)] have been analyzed with charge and energy decomposition methods using DFT calculations. Carbodiphosphoranes C(PR3)(2) are double electron pair donors having sigma- and pi-carbon lone-pair orbitals as the two highest occupied MOs.
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