Journal
ADVANCED MATERIALS
Volume 17, Issue 5, Pages 528-+Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.200401200
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Mesoporous silicon exchanges electrons extensively and reversibly with adsorbed species, e.g., NO2 and NH3. Such an exchange has been reported for systems that maintain their original p or n character. In the present case, a solid, which is a p-type semiconductor in bulk, converts to a near insulator when nanostructured. The near insulator may adopt either a p or an n nature with electron exchange, depending on the type of adsorbed molecule (see Figure).
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