Journal
ADVANCED MATERIALS
Volume 17, Issue 5, Pages 594-+Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.200401274
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The synthesis and carrier-transport properties of oligothiophene liquid-crystalline semiconductors are reported. An asymmetrically substituted terthiophene and quaterthiophene give rise to a highly ordered smectic mesophase (see Figure) with an excellent carrier mobility of up to 0.1 cm(2) V-1 s(-1) over a wide mesophase temperature range, including ambient temperatures. Ibis mobility is comparable to that of organic polycrystals.
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