Journal
SURFACE SCIENCE
Volume 578, Issue 1-3, Pages L85-L88Publisher
ELSEVIER
DOI: 10.1016/j.susc.2005.01.024
Keywords
catalysis; oxidation; surface chemical reaction; silver; copper; alkenes
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trans-Methyl styrene, an alkene that contains readily abstractable allylic H atoms, adsorbs with very similar conformations on oxygenated single crystal surfaces of Cu and Ag. Strikingly, however, subsequent reaction on silver leads merely to combustion of the organic molecule, whereas copper is extremely effective in catalyzing the epoxidation of this difficult alkene. (c) 2005 Elsevier B.V. All rights reserved.
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