Journal
ORGANIC LETTERS
Volume 7, Issue 6, Pages 987-990Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol047604i
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The complex [Ru(tpy)(pydic)] (1a) is an active catalyst for epoxidation of alkenes by aqueous 30% hydrogen peroxide in tertiary alcohols. The protocol is simple to operate and gives the corresponding epoxides in good to excellent yields. Chiral enantiopure [Ru(tpy*)(pydic)] complexes have been synthesized and successfully applied in this procedure.
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