4.8 Article

Investigations into the role of ion pairing in reactions of heteroatom-substituted cyclic oxocarbenium ions

Journal

ORGANIC LETTERS
Volume 7, Issue 6, Pages 1157-1160

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol0500620

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Funding

  1. NIGMS NIH HHS [GM61006] Funding Source: Medline

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[GRAPHICS] The O-to-C rearrangement of vinyl acetals is used to demonstrate that tight ion pairing is not involved in the stereoselective nucleophilic addition reactions of alkoxy-substituted cyclic oxocarbenium ions.

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