Journal
ORGANIC LETTERS
Volume 7, Issue 6, Pages 1039-1042Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol0474406
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A concise, modular approach for the synthesis of [1,2,4]triazolo[4,3-alpha]piperazines via condensation of highly reactive chloromethyloxadiazoles with ethylenediamines is described. NMR studies of this reaction provide evidence that suggests a novel activation mechanism for electrondeficient chloromethyloxadiazoles.
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