Journal
TETRAHEDRON LETTERS
Volume 46, Issue 12, Pages 2117-2119Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2005.01.123
Keywords
G-factors; dienol; endoperoxide; triplet oxygen; EPR spectroscopy; spin trapping
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The spontaneous addition of triplet oxygen on dienol 1, yielding encloperoxide 2, was followed by EPR/spin trapping. The use of nitroso and nitrone spin traps allowed the detection of two radical centers, showing that this reaction could likely follow a radical pathway. (C) 2005 Elsevier Ltd. All rights reserved.
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