4.0 Article

Asymmetric palladium-catalyzed benzylic nucleophilic substitution:: high enantioselectivity with the DUPHOS family ligands

Journal

TETRAHEDRON-ASYMMETRY
Volume 16, Issue 6, Pages 1183-1187

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetasy.2005.01.032

Keywords

-

Ask authors/readers for more resources

The asymmetric palladium-catalyzed benzylic reaction of 1-(2-naphthyl)ethyl acetate and its 6-methoxy substituted analogue with dimethyl malonate anion led to substitution products with up to 90% ee when the iPr-DUPHOS chiral ligand was used. (C) 2005 Elsevier Ltd. All rights reserved.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.0
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

No Data Available
No Data Available