Journal
ACS APPLIED MATERIALS & INTERFACES
Volume 7, Issue 19, Pages 10293-10307Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acsami.5b00910
Keywords
graphene; graphene dispersions; biodispersants; graphene-nanoparticle hybrids; catalytic reduction
Funding
- Spanish Ministry of Economy and Competitiveness (MINECO)
- European Regional Development Fund [MAT2011-26399, MAT2014-59592-R]
- MINECO
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The stable dispersion of graphene flakes in an aqueous medium is highly desirable for the development of materials based on this two-dimensional carbon structure, but current production protocols that make use of a number of surfactants typically suffer from limitations regarding graphene concentration or the amount of surfactant required to colloidally stabilize the sheets. Here, we demonstrate that an innocuous and readily available derivative of vitamin B2, namely the sodium salt of flavin mononucleotide (FIVINTS), is a highly efficient dispersant in the preparation of aqueous dispersions of defect-free, few-layer graphene flakes. Most notably, graphene concentrations in water as high as 60 mg mL-1 using low amounts of FMNS (FMNS/graphene mass ratios of about 0.04) could be attained, which facilitated the formation of free-standing graphene films displaying high electrical conductivity (-52000 S m ') without the need of carrying out thermal annealing or other types of post-treatment. The excellent performance of FIVII\TS as a graphene dispersant could be attributed to the combined effect of strong adsorption on the sheets through the isoalloxazine moiety of the molecule and efficient colloidal stabili7ation provided by its negatively charged phosphate group. The FMNS-stabilized graphene sheets could be decorated with nanoparticles of several noble metals (Ag, Pd, and Pt), and the resulting hybrids exhibited a high catalytic activity in the reduction of nitroarenes and electroreduction of oxygen. Overall, the present results should expedite the processing and implementation of graphene in, e.g., conductive inks, composites, and hybrid materials with practical utility in a wide range of applications.
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