Journal
JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY
Volume 53, Issue 6, Pages 2181-2184Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jf040134m
Keywords
organophosphorus derivatives; synthesis; IR; NMR; fungal pathogens; sugarcane
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Five novel organophosphorus derivatives have been synthesized by the reactions of O,O-dieth-ylchlorophosphate with piperazine dithiosemicarbazones. The derivatives have been characterized on the basis of analyses and spectral (IR, H-1 NMR) data. Fungicidal activities of these derivatives against Colletotrichum falcatum, Fusarium oxysporum, and Curvularia pallescence have been evaluated. The screening results have been correlated with the structural features of the tested compounds. Organophosphorus derivatives containing 1,4-bis(4-chlorobenzaldehyde)piperazine dithiosemicarbazone and 1,4-bis(4-methoxybenzaldehyde) piperazine dithiosemicarbazone proved to be more active than some prevalent commercial synthetic fungicides.
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