Journal
ORGANIC LETTERS
Volume 7, Issue 7, Pages 1259-1262Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol047315u
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The reaction of several phosphines with an acidic indicator gives both ion pairs and free ions. The value obtained for the pK(8) of tribenzylphosphine is shown to be reasonable by MO computations. An important limitation is demonstrated for the Fuoss equation of dissociation of ion pairs.
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